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Gold complexes trans-influence

The trans influence of a ligand is the ability of a ligand to weaken the bond trans to itself in a complex. Gold(I) and gold(III) complexes are, in the simplest treatment, considered to use sp and dsp hybrid orbitals in forming linear and square planar complexes respectively. A good o donor, L, tends to concentrate gold 6s character in the AuL bond and the trans bond must then overlap with an orbital of low s character. A weaker and more ionic bond is then formed. [Pg.5742]

See other pages where Gold complexes trans-influence is mentioned: [Pg.133]    [Pg.59]    [Pg.38]    [Pg.861]    [Pg.869]    [Pg.869]    [Pg.869]    [Pg.887]    [Pg.95]    [Pg.97]    [Pg.97]    [Pg.99]    [Pg.254]    [Pg.34]    [Pg.38]    [Pg.15]    [Pg.272]    [Pg.561]    [Pg.5742]    [Pg.5742]    [Pg.5760]    [Pg.6048]    [Pg.15]    [Pg.71]    [Pg.214]    [Pg.439]    [Pg.157]    [Pg.29]   
See also in sourсe #XX -- [ Pg.869 ]



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