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Gold complexes boron bonds

COMPLEXES WITH GOLD-MAIN GROUP METAL BONDS 55.22.1 Complexes with Gold-Boron Bonds... [Pg.903]

Novel boron-gold bonds containing complexes are realized in two borido clusters. Addition of [HFe4(CO)i2BH] ppn to xs (PPhjIAuCl in CH2CI2 forms the green-brown, air-sensitive Fe4(CO) 2(AuPPh,)2BH ... [Pg.49]

Au-B bonds are also present in metal clusters with intersticial or peripheral boron atoms. An example is the cluster [Fe4(CO)12BH(AuPPh3)2], which was prepared by reaction of [AuCl(PPh3)] with the carbonyl iron dihydride. With the oxonium salt the reaction proceeds to the trinuclear gold derivative [Fe4(CO)12B(AuPPh3)3] (357).2063-2070 The ruthenium analogues and complexes with other ligands have been also synthesized as, for example, (358).2071-2079... [Pg.1025]

See other pages where Gold complexes boron bonds is mentioned: [Pg.158]    [Pg.133]    [Pg.1025]    [Pg.862]    [Pg.39]    [Pg.47]    [Pg.49]    [Pg.244]    [Pg.5735]    [Pg.6048]    [Pg.408]    [Pg.33]    [Pg.139]    [Pg.212]    [Pg.570]    [Pg.33]    [Pg.447]    [Pg.385]    [Pg.202]    [Pg.446]    [Pg.204]    [Pg.31]    [Pg.54]    [Pg.409]    [Pg.159]    [Pg.30]    [Pg.128]   
See also in sourсe #XX -- [ Pg.903 ]



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