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Gold clusters fluxionality

Similar fluxional processes are believed to operate in heteronuclear gold cluster compounds and these may be slowed down by lowering the... [Pg.346]

From the Mossbauer results on Aujj, the thermodynamic behavior of AU55, as well as AugLi " and AuiiL7(SCN)j, at temperatures between 2 K and 30 K can be understood on the basis of the center-of-mass motion of the whole gold core of the material, within the matrix formed by the surrounding ligands. Furthermore, none of these clusters are in the liquid (fluxional) state on the MES time scale, up to at least 30 K. [Pg.34]

See other pages where Gold clusters fluxionality is mentioned: [Pg.346]    [Pg.25]    [Pg.25]    [Pg.26]    [Pg.147]    [Pg.1030]    [Pg.33]    [Pg.261]    [Pg.909]    [Pg.321]    [Pg.322]    [Pg.22]    [Pg.33]    [Pg.129]    [Pg.15]    [Pg.16]    [Pg.21]    [Pg.1062]    [Pg.1064]    [Pg.185]   
See also in sourсe #XX -- [ Pg.25 ]



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