Glycosylmanganese pentacarbonyl

An interesting study on glycosylmanganese pentacarbonyl complexes, (glycosyl)Mn(CO)5, has been performed by DeShong et al The complexes have been characterised, among others, by /cMn couplings and Mn NMR chemical shifts /c(i)Mn of 45-48 Hz have been reported for these compounds. 

Glycosylmanganese pentacarbonyl complexes have been characterized on the basis of H-, and Mn-NMR spectral data, and ten tungstate and seven molybdate complexes of D-gulonic acid in aqueous solutions have been identified by multinuclear NMR studies ( H, O, Mo,... 

Having prepared glycosylmanganese pentacarbonyl complexes, we turned our attention to demonstrating that these complexes would undergo the processes... 

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