Glycosylation ferric chloride-catalyzed

The ferric chloride-catalyzed glycosylation was conducted by treating compounds 2, and (1 mol equiv.) with benzyl or... 

Kiso, M, Anderson, L, The ferric chloride-catalyzed glycosylation of alcohols by 2-acylamido-2-deoxy-p-D-glucopyranose 1-acetates, Carbohydr. Res., 72, C12-C14, 1979. 

It has been reported that some simple, synthetic glycollpids, such as II-fatty acylated 2-amino-2-deoxy-D-glucose derivatives, exhibit potent immunostimulatory activities (5). We first examined a facile preparation of N-fatty acylated 2-amino-2-deoxy-D-glucopyranosides, which would be key intermediates for the synthesis of lipid A and its analogs (Figure 2). For this purpose, the one-step glycosylation catalyzed by ferric chloride (6, 7) was employed. 

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See also in sourсe #XX -- [ ]

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