Glycosyl Dimethylphosphinothioates

Yamanoi, T, Nakamura, K, Takeyama, H, Yanagihara, K, Inazu, T, New synthetic methods and reagents for complex carbohydrates. 8. Stereoselective a- and 3-mannopyranoside formation from glycosyl dimethylphosphinothioates with the C-2 axial benzyloxyl group. Bull. Chem. Soc. Jpn., 67, 1359-1366, 1994. 

Branched Homotrisaccharides.— By use of glycosyl dimethylphosphinothioate derivatives the branched mannotriose a-D-Maiip-(l- 6)-[a-D-Manp-(l->3)]-D-Man has been prepared. ... 

Inazu, T, Yamanoi, T, A novel glycosylation reaction of 2-amino-2-deoxy-D-glucopyranose using dimethylphosphinothioate, Chem. Lett., 69-72, 1989. 

---