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Glycosides intramolecular

Ziegler and coworkers prearranged a glycoside by employing a succinyl tether between C-6 of a mannosyl donor and C-3 of glucosyl acceptor [151,152]. They found that the nature of the glycosyl acceptor and the length of the tether affected the anomeric selectivity of the intramolecular mannosylation (Scheme 4.4d) [153]. [Pg.214]

Table 5.6A Intramolecular glycosylations via prearranged glycosides - glucose donors. Table 5.6A Intramolecular glycosylations via prearranged glycosides - glucose donors.
Yet another approach uses peptides as tethers for intramolecular glycosylations via prearranged glycosides (Scheme 5.113) [326,327]. The regio- and anomeric selectivity of the intramolecular glycosylation depends on the amino acid sequence of the peptide, which links glycosyl donor and acceptor. [Pg.428]


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See also in sourсe #XX -- [ Pg.274 ]




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Intramolecular General Acid Catalysis of Glycoside Hydrolysis

Intramolecular Glycosidations

Intramolecular glycosidation

Intramolecular glycosidation

Intramolecular glycosidation reactions

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