Glycals furanose-derived

Scheme 41 Synthesis a furanose-fused butyrolactone from a glycal-derived cyclopropane...

Other avenues of research were not ignored, however, as is indicated by the preparation of the first furanose-related glycal and the study of inversions in the cyclitol series by treatment of their esters with liquid hydrogen fluoride. Then, in the mid-sixties, Dr. Fletcher began to turn to the chemistry of acylamidodeoxyhexoses. Together with Drs. Nevenka Pravdic and T. D- Inch, he prepared 1,2-ox-azoline derivatives of such carbohydrates. This led to a method for... 

Ness, R. K., and H. G. Fletcher, Jr. 2-Deoxy-D-er> f/iro-pentose. X. Synthesis of l,4-Anhydro-3,5-di-0-benzoyl-2-deoxy-D-er> //iro-pentose-l-enol. Derivatives of a Furanose-related Glycal. J. Organ. Chem. (U.S.A.) 28, 435 (1963) Haga, M., and R. K. Ness Preparation and Properties of 3,5-Di-0-p-anisoyl-l,2-dideoxy-D-er> t/iro-pentofuranose-l-ene. Various p-Anisoylated Derivatives of D-Ribofuranose. J. Organ. Chem. (U. S. A.) 30, 158 (1965). 

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