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Glucopyranoside with nitrogen dioxide

A. Assarsson and O. Theander, The oxidation of glycosides. XIV. The oxidation of methyl /i-D-glucopyranoside with nitrogen dioxide, Acta Chem. Scand., 18 (1964) 553-580. [Pg.364]

The oxidation and subsequent hydrolysis of starch to a-D-glucofuran-urono-6,3-lactone has been studied nitric acid alone, or in combination with nitrites, and nitrogen dioxide, have been examined as oxidants. Good results were obtained for oxidations with nitric acid in the presence of formic acid. A number of patents have been issued on these topics (Ref. 1, pp. 1137, 1138). Treatment of methyl /1-D-glucopyranoside with liquid nitrogen dioxide for 5 h at 12 °C afforded mostly D-glucaric acid, and three isomeric hexopyranosiduloses accounted for an additional 6% of the products.119... [Pg.341]

See other pages where Glucopyranoside with nitrogen dioxide is mentioned: [Pg.241]    [Pg.63]    [Pg.265]    [Pg.240]    [Pg.240]    [Pg.240]    [Pg.241]    [Pg.270]    [Pg.272]   
See also in sourсe #XX -- [ Pg.270 , Pg.271 ]



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