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Glucals, rearrangement

Compound 61 was derived from 3,4,6-tri-0-acetyl-2-deoxy-n-arafet no-hexopyranosyl bromide, which was produced by direct addition of hydrogen bromide to the double bond. The bromodeoxy sugar 62 was, presumably, formed by addition to a 2,3-unsaturated, rearrangement product of the type known118 to arise from tri-O-acetyl-D-glucal in the presence of acid. [Pg.264]

V. Bolitt, C. Mioskowski, S. G. Lee, and J. R. Falck, Direct preparation of 2-deoxy-D-gluco-pyranosides from glucals without Ferrier rearrangement, J. Org. Chem., 55 (1990) 5812-5813. [Pg.202]


See other pages where Glucals, rearrangement is mentioned: [Pg.160]    [Pg.162]    [Pg.164]    [Pg.164]    [Pg.39]    [Pg.44]    [Pg.47]    [Pg.49]    [Pg.361]    [Pg.372]    [Pg.374]    [Pg.233]    [Pg.555]    [Pg.227]    [Pg.142]    [Pg.256]    [Pg.158]    [Pg.205]    [Pg.262]    [Pg.197]    [Pg.148]    [Pg.658]    [Pg.72]    [Pg.361]    [Pg.219]    [Pg.58]    [Pg.59]    [Pg.67]    [Pg.72]    [Pg.72]    [Pg.73]    [Pg.76]    [Pg.77]    [Pg.78]    [Pg.112]    [Pg.236]    [Pg.368]    [Pg.9]    [Pg.209]    [Pg.211]    [Pg.220]    [Pg.55]    [Pg.184]    [Pg.200]   
See also in sourсe #XX -- [ Pg.555 ]

See also in sourсe #XX -- [ Pg.555 ]

See also in sourсe #XX -- [ Pg.98 , Pg.99 , Pg.555 , Pg.655 ]




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Glucals

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