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Polystyrene glassy, molecular motion

Molecular Motion in amorphous atactic polystyrene (PS) is more complicated and a number of relaxation processes, a through 5 have been detected by various techniques as reviewed recently by Sillescu74). Of course, motions above and below the glass transition temperature Tg have to be treated separately, as well as chain and side group mobility, respectively. Motion well above Tg as well as phenyl motion in the glassy state, involving rapid 180° jumps around their axes to the backbone has been discussed in detail in Ref.17). Here we will concentrate on chain mobility in the vicinity of the glass transition. [Pg.42]

J Schaefer, MD Sefcik, EO Stejskal, RA McKay, WT Dixon, RE Cais. Molecular motion in glassy polystyrenes. Macromolecules 17 1107-1118, 1984. [Pg.512]


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See also in sourсe #XX -- [ Pg.43 , Pg.44 , Pg.45 , Pg.46 , Pg.47 , Pg.48 , Pg.49 , Pg.50 , Pg.51 , Pg.52 , Pg.53 ]

See also in sourсe #XX -- [ Pg.43 , Pg.44 , Pg.45 , Pg.46 , Pg.47 , Pg.48 , Pg.49 , Pg.50 , Pg.51 , Pg.52 , Pg.53 ]




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