Gibbs free energy profiles transition states

The Gibbs free energy reaction profiles in Fig. 16 have been calculated from the results in Table 16 and the mechanism in (30) and refer to reaction in a 1 1 2-methylphenol buffer at buffer concentrations of 0.001 and 0.1 moldm" (Fig. 16(a) and (b), respectively). TS(1) is the transition state for opening of the intramolecular hydrogen bond and TS(2) is the transition... 

Fig. 4 Free energy profile for interaction. Acf and AG are the changes in Gibbs free energy required for the formation of the transition state starting from reactants and complex, respectively. AG° is the change in Gibbs free energy between reactants and complex...

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