Gibbs ensemble Monte Carlo for phase equilibria

GCMC generates a Markov chain of microscopic states that sample this probability distribution. There are two types of move in GCMC  

Thermal equilibration moves. These are the same moves in constant NVT phase space with particle displacements and acceptance rules, 

Chemical equilibration moves. These are particle insertion and deletion moves  

Using these acceptance rules, the system maintains constant jx, T, T. 

6 Gibbs ensemble Monte Carlo for phase equilibria 

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