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Gibbs-Boltzmann statistical probability

When g = 1 the extensivity of the entropy can be used to derive the Boltzmann entropy equation 5 = fc In W in the microcanonical ensemble. When g 1, it is the odd property that the generalization of the entropy Sq is not extensive that leads to the peculiar form of the probability distribution. The non-extensivity of Sq has led to speculation that Tsallis statistics may be applicable to gravitational systems where interaction length scales comparable to the system size violate the assumptions underlying Gibbs-Boltzmann statistics. [4]... [Pg.199]

In modem physics, there exist alternative theories for the equilibrium statistical mechanics [1, 2] based on the generalized statistical entropy [3-12]. They are compatible with the second part of the second law of thermodynamics, i.e., the maximum entropy principle [13-14], which leads to uncertainty in the definition of the statistical entropy and consequently the equilibrium probability density functions. This means that the equilibrium statistical mechanics is in a crisis. Thus, the requirements of the equilibrium thermodynamics shall have an exclusive role in selection of the right theory for the equilibrium statistical mechanics. The main difficulty in foundation of the statistical mechanics based on the generalized statistical entropy, i.e., the deformed Boltzmann-Gibbs entropy, is the problem of its connection with the equilibrium thermodynamics. The proof of the zero law of thermodynamics and the principle of additivity... [Pg.303]

Looking at the phase space not as a succession in time of microscopic states that follow Newtonian mechanics, but as an ensemble of microscopic states with probabilities that depend on the macroscopic state, Gibbs and Boltzmann set the foundation of statistical thermodynanucs, which provides a direct connection between classical thermodynamics and microscopic properties. [Pg.8]


See other pages where Gibbs-Boltzmann statistical probability is mentioned: [Pg.2187]    [Pg.2188]    [Pg.2187]    [Pg.2188]    [Pg.79]    [Pg.1495]    [Pg.100]    [Pg.276]    [Pg.59]    [Pg.93]    [Pg.514]    [Pg.177]    [Pg.177]    [Pg.156]    [Pg.315]    [Pg.315]    [Pg.6]    [Pg.160]    [Pg.132]    [Pg.213]    [Pg.43]    [Pg.305]    [Pg.185]    [Pg.583]   
See also in sourсe #XX -- [ Pg.3 , Pg.2187 ]




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