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Gibbs-Bogoliubov variational principle

It should be noted that these equations are to be solved for each position of the centroid q. The frequency in Eq. (2.27) is the same as the effective frequency obtained for the optimized LHO reference system using the path-integral centroid density version of the Gibbs-Bogoliubov variational method [1, pp. 303-307 2, pp. 86-96], Correspondingly, Eqs. (2.27) and (2.28) are exactly the same as those in the quadratic effective potential theory [1,21-23], The derivation above does not make use of the variational principle but, instead, is the result of the vertex renormalization procedure. The diagrammatic analysis thus provides a method of systematic identification and evaluation of the corrections to the variational theory [3],... [Pg.150]


See other pages where Gibbs-Bogoliubov variational principle is mentioned: [Pg.116]    [Pg.121]    [Pg.139]    [Pg.190]    [Pg.373]    [Pg.100]    [Pg.116]    [Pg.121]    [Pg.139]    [Pg.190]    [Pg.373]    [Pg.100]    [Pg.86]    [Pg.406]   


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