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Germyl radicals polymeric

These polymeric germylmercurials decompose to generate" germyl radicals, [RjGe] germylenes, RjGe and germynes, RGe. [Pg.452]

Kobayashi s group also conducted the oxidation-reduction polymerization (Scheme 44), where the germylene (178) acts as a reductant and the p-benzoquinone (179) as an oxidant - This polymerization occurs at 78°C to give high MW polymers (>10 ) within 1 h. These copolymers (180) were stable at room temperature and were resistant to moisture and air. The mechanism of this reaction was studied by ESR spectroscopy. It was foimd that the reaction proceeded via a biradical mechanism involving a germyl and a semiquinone radical. ... [Pg.238]

See other pages where Germyl radicals polymeric is mentioned: [Pg.137]    [Pg.98]    [Pg.745]    [Pg.1529]    [Pg.1572]    [Pg.1529]    [Pg.1572]    [Pg.137]    [Pg.67]    [Pg.937]    [Pg.611]    [Pg.724]    [Pg.33]    [Pg.221]   
See also in sourсe #XX -- [ Pg.1572 ]

See also in sourсe #XX -- [ Pg.1572 ]



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