Gerischer

C. W. Tobias and H. Gerischer, Advances in Electrochemical S cience and Engineering, VCH, New York, from 1990. 

Figure 42. Scheme comparing expected potential-independent charge-transfer rates from Marcus-Gerischer theory of interfacia) electron transfer (left) with possible mechanisms for explaining the experimental observation of potential-dependent electron-transfer rates (right) a potential-dependent concentration of surface states, or a charge-transfer rate that depends on the thermodynamic force (electric potential difference) in the interface. 

H. Gerischer, and W. Ekardt, Fermi levels in electrolytes and the absolute scale of redox potentials, Appl. Phys. Lett. 43(4), 393-395 (1983). 

A number of recent cell designs have used particulate electrodes. The early versions had slurry electrodes (Butler and Fawcett, 1964 Gerischer, 1963) but more recently the electrodes have been packed or... 

Barl Barz, F., Bernstein, Ch., Vielstich W. Advances in Electrochemistry and Electrochemical Engineering, Vol. 13, Gerischer, H. (ed.). New York John Wiley, 1984. 

Andre, E., Brink, M., Gerisch, G., Isenberg, G., Noegel, A., Schleicher, M., Segall, J.E., Wallraff, E. (1989). A Dictyostelium mutant deficient in severin, an F-actin fragmenting protein, shows normal motility and chemotaxis. J. Cell Biol. 108, 985-995. 

The prediction of which semiconductor materials are suitable as electrodes for a given photoelectrolysis reaction would be straightforward if the energy position of the bands at the electrode surface remained fixed with respect to the solution redox levels and independent of the redox species in the solution. Gerischer... 

Actually, G. C. Barker was the first to suggest the idea of stabrhzing the n-CdS photoanode by a sulfide solution - see discussion in Gerischer [44]. 

Gerischer H (1975) Electrochemical photo and solar cells. Principles and some experiments. Electroanal Chem Interfacial Electrochem 58 263-274... 

Gerischer H (1970) Semiconductor Electrochemistry. In Eyring H (ed) Physical Chemistry - An advanced treatise Vol IXA, Academic Press, New York... 

Diaz AF, Logan JA(1980)Electroactive polyanihne films. JElectroanalChem 111 111-114 Noufi R, Nozik AJ, White J, Warren LF (1982) Enhanced stability of photoelectrodes with electrogenerated polyanUine films. J Electrochem Soc 129 2261-2265 Noufi R, Tench D, Warren LE (1981) Protection of semiconductor photoanodes with photoelectrochemicaUy generated polypyrrole films. J Electrochem Soc 128 2596-2599 Jaeger CD, Fan FRF, Bard AJ (1980) Semiconductor electrodes. 26. Spectral sensitization of semiconductors with phthalocyanine. J Am Chem Soc 102 2592-2598 Gerischer H (1977) On the stability of semiconductor electrodes against photodecomposition. J Electroanal Chem 82 133-143... 

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