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Geometrical distortions transition metal complexes

Slovokhotov, Yu.L. and Struchkov, Yu.T (1984) X-ray crystal structure of a distorted tetrahedral cluster in the salt [(Ph P)4Au4N] BF4 . Geometrical indication of stable electronic configurations in post-transition metal complexes and the magic number 18-e in centred gold clusters. Journal of Organometallic Chemistry, 177, 143-146. [Pg.234]

The geometric distortion of nonlinear complexes of certain transition metal ions to remove degeneracy. For example, Mn(III) in octahedral coordination is expected to have an electronic configuration of Elongation along one axis of the octahe-... [Pg.6]

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Geometric distortion

Geometrical distortions

Geometrical distortions complexes