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Geometric Phase Effects in Chemical

GEOMETRIC PHASE EFFECTS IN CHEMICAL REACTION DYNAMICS... [Pg.521]

Geometric Phase Effects in Chemical Reaction Dynamics... [Pg.523]

Kuppermann A and Wu Y S M 1993 The geometric phase effect shows up in chemical reactions Chem. [Pg.2323]

The geometric phase effect associated with chemical reactions [166] and with the motion of electrons in magnetic fields [167] was generalized in 1984 by Berry [168] to systems which are transported around a loop or circuit C in parameter space. If H is the system s Hamiltonian and R a set of parametric variables on which H depends, he showed that an eigenstate of when the system is transported slowly (i.e., adiabatically) around C, will acquire a geometrical phase factor independent of time, in addition to the familiar... [Pg.119]

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