Generation of a-Silyl Carbanions from Allylsilanes

Stereoselective synthesis of 1,4-disubstituted 1,3-dienes from aldehydes has also been reported [232, 233]. The stereoselective synthesis of j8-hydroxy-a-(l-alkenyl)- 

3 Generation of a-Silyl Carbanions and their Peterson Reactions 57 But)K 

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Scheme 2.79. Stereoselective synthesis of a,jS-unsaturated nitriles by the Peterson reaction. 2.3.2.14 Generation of a-Silyl Carbanions from Allylsilanes...

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