General spin Hamiltonians

S=l. For =1, the general spin Hamiltonian without hyperfine interaction is... [Pg.125]

J. 5=f The general spin Hamiltonian, excluding hyperfine interactions, is... [Pg.129]

A Jahn-Teller system modeled through generalized spin Hamiltonian the... [Pg.273]

A JAHN-TELLER SYSTEM MODELED THROUGH GENERALIZED SPIN HAMILTONIAN THE H3 MOLECULE... [Pg.276]

A more general spin Hamiltonian which describes the effect of spin-orbit coupling to second order is... [Pg.77]

A more general spin Hamiltonian of the form (3.9) is applied when zero-field splittings (S > V2), anisotropic hyperfine interactions (/ 0), and nuclear quadrupole couplings (/ > 1) occur. [Pg.144]

Mathematically these interactions can be written using the spin Hamiltonian formalism. For an isolated paramagnetic center (A) a general spin Hamiltonian (H) [1,2,12] is ... [Pg.108]

A general spin Hamiltonian for a nitroxide spin label is given by ... [Pg.111]

The general spin Hamiltonian was given by Eq. (2), in which the interaction parameters were written in the general tensor form. The total hyperfine tensor A can be represented by a 3 X 3 matrix that connects the three components each of the electron spin angular momentum and the nuclear spin angular momentum. The hyperfine tensor is a real matrix and can always be diagonalized. Thus a general tensor referenced to an x-y-z axis system can be written as... [Pg.128]

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