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General and theoretical aspects

The reactions of monosaccharides in aqueous alkaline solution is the subject of a review covering initial transformations, alkaline degradation and the Influence of reaction variables on product for-1 [Pg.2]

Molecular orbital calculations have been carried out in an investigation of the mechanism of mutarotation of oC-D-glucopyranose. The CNDO/2 results were in agreement with experiment for acid- and base- [Pg.2]

A far-reaching communication has concluded that there is an intrinsic energy difference between enantiomeric chemical species. The results, from an initio calculation, depend on parity-violating weak interactions due primarily to the electron-neutron potential component of the weak neutral current present in atomic nuclei. Application to the model sugar, hydrated glyceraldehyde, indicated that the D-enantiomer is of lower energy, which, if taken as a energy difference, corresponds to an enantiomeric excess [Pg.2]


G. Berthier and J. Serre, "General and theoretical aspects of the carbonyl group" in The Chemistry of the Carbonyl Group. Interscience, 1966. [Pg.53]


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General and Theoretical

General aspects

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