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Gem-Dimethyloxazoline

X-Ray Analysis of Pd(ll) Complexes Coordinated by P,N Ligand Having Achiral gem-Dimethyloxazoline... [Pg.300]

Catalytic asymmetric alkaloid synthesis remains a challenge [114], in spite of the pharmaceutical importance of kainic acid [115,116] etc. Chiral transition metal complexes are the catalysts [117] of choice for cyclization of enynes, dienes [118, 119], or diynes [120]. With axially chiral P,N ligands having an achiral gem-dimethyloxazoline unit, alkaloid synthesis can be attained via ene-type cyclization [121]. [Pg.302]

Hatano M, Yamanaka M, Mikami K (2003) A new N,P-ligand with achiral gem-dimethyloxazoline for palladium(II)-catalyzed cyclization of 1,6-enynes transition state probe for the N/C trans mode in Mizoroki-Heck-type C-C bond formation. Eur J Org Chem 2552-2555... [Pg.339]

See other pages where Gem-Dimethyloxazoline is mentioned: [Pg.279]    [Pg.279]    [Pg.298]    [Pg.299]    [Pg.279]    [Pg.279]    [Pg.298]    [Pg.299]   
See also in sourсe #XX -- [ Pg.298 ]



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