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Gaussian fluctuation formula

Levy, R. M., Belhadj, M., Kitchen, D. B. Gaussian fluctuation formula for electrostatic free energy changes. J. Chem. Phys. 95 (1991) 3627-3633... [Pg.162]

R. M. Levy, M. Belhadj, and D. B. Kitchen, ]. Ghem. Phys., 95, 3627 (1991). Gaussian Fluctuation Formula for Electrostatic Free Energy Changes in Solution. [Pg.126]

When the distribution being averaged over is dynamic [29] but classical with Gaussian fluctuations x(f), the gammas representing the homogeneous widths of different components should be omitted from the formulas and the average in Eq. (44) must be replaced by... [Pg.29]

The success of Flory s formula is due to the mutual compensation of the effects not taken into account. In effect, the entropy component in Equation 111 or 141 is overestimated owing to the Gaussian statistics applied. The energy component is also overestimated by a close vedue due to the neglect of the correlation of segment density fluctuations in a coil. [Pg.276]


See other pages where Gaussian fluctuation formula is mentioned: [Pg.267]    [Pg.267]    [Pg.196]    [Pg.59]    [Pg.901]    [Pg.39]    [Pg.215]    [Pg.344]    [Pg.188]    [Pg.215]    [Pg.694]    [Pg.700]    [Pg.852]    [Pg.209]    [Pg.443]    [Pg.276]    [Pg.328]   
See also in sourсe #XX -- [ Pg.269 ]




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