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Gas phase heterolysis

Although the geometric relationship suggested by Shiner and by Sunko and their co-workers clearly demonstrates that hyperconjugation is the major contributor to the secondary /3-deuterium KIE in carbocation reactions, Williams (1985) has suggested that there is a significant inductive component to these KIEs. Williams used ab initio MO methods to calculate the geometries of the substrates and the isopropyl carbocation formed in a gas-phase heterolysis (30) of series of isopropyl derivatives at the RHF/4-31G level. [Pg.200]

Free radicals, identification by electron spin resonance, 1, 284 Gas-phase heterolysis, 3, 91... [Pg.404]

See other pages where Gas phase heterolysis is mentioned: [Pg.337]    [Pg.356]    [Pg.301]    [Pg.280]    [Pg.349]    [Pg.347]    [Pg.3]    [Pg.301]    [Pg.312]    [Pg.386]    [Pg.320]    [Pg.91]    [Pg.93]    [Pg.95]    [Pg.97]    [Pg.99]    [Pg.101]    [Pg.105]    [Pg.107]    [Pg.111]    [Pg.113]    [Pg.115]    [Pg.117]    [Pg.119]    [Pg.121]    [Pg.278]   
See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]

See also in sourсe #XX -- [ Pg.3 , Pg.91 ]



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Heterolysis

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