Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Third heterobimetallic asymmetric catalyst reported by Shibasaki et al., gallium-sodium-BINOL complex (GaSB) 26 and indium-potassium-BINOL complex (InPB), are also rather effective catalysts for asymmetric Michael reactions, and GaSB was better than InPB in terms of enantioselectivity. The GaSB catalyst was prepared from GaCl3, NaO Bu (4 mol equiv. to... [Pg.584]

See other pages where Gallium-sodium-BINOL is mentioned: [Pg.234] [Pg.234]