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Ga-Li-linked BINOL

Complexes of other metals such as gallium, indium, lead, and antimony have also been used as Lewis acids. Catalytic enantioselective meso-epoxide ring-opening reactions using a chiral gallium(III) catalyst (Ga-Li-linked-BINOL) have been reported (Scheme 84).348 The chemical yields are much improved by linking two BINOL units. [Pg.435]

Binaphthalene-2,2 -diol-gallium/IM 2-Aryloxy alcohols. meso-Epoxidc Ga—Li linked BINOL complex with high... [Pg.26]

Aryloxy alcohols. mc5o-Epoxides are opened by phenols in the presence of the Ga—Li linked BINOL complex with high enantioselectivity. [Pg.27]


See other pages where Ga-Li-linked BINOL is mentioned: [Pg.242]    [Pg.115]    [Pg.116]    [Pg.242]    [Pg.115]    [Pg.116]   
See also in sourсe #XX -- [ Pg.116 ]




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BINOL

BINOL, linked

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