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Functionalized Grignard reagents acylation

Decomposition of azo compounds and peroxides provides the alkoxyamine by the nitroxide-trapping of the primary radicals [29]. The radicals produced by hydrogen abstraction with oxy radicals are also trapped by the nitroxide [242, 243]. In the photoreaction, alkoxyamines were isolated with high yields [244]. The reactions of Grignard reagents with nitroxides [215] and the coupling reaction of sodium nitroxides with bromo compounds [234,235] are also used. The hydrolysis of 56 followed by the reaction with acyl or alkyl halides afforded alkoxyamines with various functional groups,63 (Eq. 68) [245-251] ... [Pg.118]

A variety of functional transformations occurring far from the SMA framework have been described. Acylation of a silyl ether, sodium borohydride or LAH reduction of an ester into a carbinol, oxidation of a carbinol into an aldehyde or a ketone, and the addition of Grignard reagents to a carbonyl are some examples.95,168,255... [Pg.260]

In general, thiocarbonyl halides (59) function as thioacylation reagents with a variety of nucleophiles to yield the appropriate thio derivatives (60) (Scheme 31). For example, (59) on condensation with thiols, amines, potassium cyanide or potassium thiocyanide yields the corresponding thio compounds (60). Thiolocarboxylic acids (50) characteristically acylate alcohols and amines with desulfuration (Scheme 32). Dithiocarboxylic acid esters (54b) react with organolithium or Grignard reagents to give the dithioketals (61) after treatment with an alkyl halide (Scheme 33). [Pg.137]


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See also in sourсe #XX -- [ Pg.559 , Pg.601 , Pg.603 ]




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Acylating reagents

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