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Functionalized benzylic manganese reagents

Homocoupling Reactions of Functionalized Benzylic Manganese Reagents... [Pg.332]

The resulting benzylic manganese reagents were found to undergo a variety of cross-coupling reactions. It was also found that homocoupled products of functionalized benzyl halides could be readily prepared depending on reaction conditions. [Pg.321]

Oxidation of oxygen functions. DDQ is useful for the selective oxidation of allylic " and benzylic alcohols. The reagent has the advantage of not showing the variability encountered with active manganese dioxide. It dehydrogenates 2-hydroxymethylene-3 ketosteroids in about 50% yield. The steroid is treated in dioxane solution at room temperature with 1.1 -1.5 equivalents of DDQ for 1 -5 min.. [Pg.842]

See other pages where Functionalized benzylic manganese reagents is mentioned: [Pg.326]    [Pg.326]    [Pg.308]    [Pg.336]    [Pg.296]    [Pg.299]    [Pg.259]    [Pg.385]    [Pg.614]    [Pg.355]    [Pg.355]    [Pg.181]    [Pg.614]    [Pg.214]    [Pg.136]   
See also in sourсe #XX -- [ Pg.332 , Pg.334 ]



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Benzyl functions

Benzyl reagent

Benzylic functionalization

Functionalized benzylic manganese

Homocoupling Reactions of Functionalized Benzylic Manganese Reagents

Manganese function

Manganese reagents

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