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Functional Group Conversion, Pages

Stopping the reaction before completion. This method is very similar to the asymmetric syntheses discussed on page 132. A method has been developed to evaluate the enantiomeric ratio of kinetic resolution using only the extent of substrate conversion. An important application of this method is the resolution of racemic alkenes by treatment with optically active diisopinocampheylborane, since alkenes do not easily lend themselves to conversion to diastereomers if no other functional groups are present. Another example is the resolution of allylic alcohols such as (56 with one... [Pg.154]


See other pages where Functional Group Conversion, Pages is mentioned: [Pg.1627]    [Pg.138]    [Pg.39]    [Pg.1258]    [Pg.2344]    [Pg.1897]    [Pg.658]    [Pg.433]    [Pg.46]    [Pg.65]    [Pg.984]    [Pg.533]    [Pg.983]   


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Conversion functions

Function group conversion

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