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Fullerene cages, opening

A light-induced oxygen incision of Cgg was reported to lead to an opening of the fullerene cage [40,41]. For more examples of ring-opening reactions see Chapter 11. [Pg.256]

Schick G., Hirsch A., Mauser H., Clark T. (1996) Opening and closure of the fullerene cage in cis-1-bisimino adducts of Ceo - the influence of the addition pattern and addend, Chem. Eur. J., 2, 935-942. [Pg.787]

Scheme 1.8. Controlled opening of the fullerene cage by self-sensitized photooxygenation of an azahomo[60]fullerene derivative and subsequent add-induced formation of a dimeric aza[60]fullerene. Scheme 1.8. Controlled opening of the fullerene cage by self-sensitized photooxygenation of an azahomo[60]fullerene derivative and subsequent add-induced formation of a dimeric aza[60]fullerene.
Scheme 1.10. Achiral dimeric aza[70]fullerenes and their chiral cage-opened ketolactam precursors. The third ketolactam (right) is expected to afford a mixture of meso- and d, Z-6,6 -bi-5-aza[70]fullerene. Scheme 1.10. Achiral dimeric aza[70]fullerenes and their chiral cage-opened ketolactam precursors. The third ketolactam (right) is expected to afford a mixture of meso- and d, Z-6,6 -bi-5-aza[70]fullerene.
Murata, M., Ochi, Y, Tanabe, F. et al. (2008) Internal magnetic fields of dianions of fullerene C o and its cage-opened derivatives studied with encapsulated H2 as an NMR probe. Angewandte Chemie International Edition, 47, 2039-2041. [Pg.300]

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See also in sourсe #XX -- [ Pg.37 ]



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