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Free radicals acyloxy, decarboxylation

The studies of Bartlett and his coworkers (1) on decompositions of Jb-butyl peresters of a wide range of carboxylic acids clearly showed two mechanistic pathways for the production of free radicals. The first mechanism is the simple homolysis of the 0-0 bond to give an acyloxy -butoxy (pair) intermediate which can decarboxylate in a subsequent step. This mechanism (A-1) pertains to the unimolecular free radical pro-... [Pg.134]

See other pages where Free radicals acyloxy, decarboxylation is mentioned: [Pg.892]    [Pg.260]    [Pg.1646]    [Pg.1656]    [Pg.331]    [Pg.239]   
See also in sourсe #XX -- [ Pg.670 , Pg.671 , Pg.674 , Pg.726 ]

See also in sourсe #XX -- [ Pg.659 , Pg.660 , Pg.706 ]

See also in sourсe #XX -- [ Pg.670 , Pg.671 , Pg.674 , Pg.726 ]



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