Free energy ofhydration

Finally, this section ends with a reminder that heats, entropies, and free energies ofhydration depend on concentration (Fig. 2.14) and that there are significant changes in values at very low concentrations. It is the latter values that are the desired quantities because at high concentrations the heats and free energies are influenced not only by ion-solvent interactions (which is the objective of the venture) but also by interionic forces, which are much in evidence (Chapter 3) at finite concentrations. 

Gibbs Free Energy ofHydration or Salt Cation or Anion) kj/niol... 

Fu J, Liu Y, WuJ Molecular density functional theory for multiscale modeling ofhydration free energy, Chem Eng Sci 126 370-382, 2015b. 

Ratkova EL, Chuev GN, Sergiievskyi VP, Fedorov MV An accurate prediction ofhydration free energies by combination of molecular integral equations theory with structural descriptors, J Phys Chem B 114(37) 12068—12079, 2010. 

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