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Fragment concepts frontier orbitals

In the first three chapters, instances were noted where the number, symmetry characteristics and occupation numbers of the frontier orbitals of a transition-metal fragment were similar to those of a main-group fragment. Such fragments are said to be isolobal to emphasize similar bonding capabilities. Since its enunciation by Hoffmann and Mingos, the concept has been used effectively for the analysis of both organometallic and cluster problems. Let s explore the idea in a more systematic... [Pg.139]

See other pages where Fragment concepts frontier orbitals is mentioned: [Pg.317]    [Pg.149]    [Pg.360]    [Pg.30]    [Pg.195]    [Pg.198]    [Pg.106]    [Pg.867]    [Pg.256]    [Pg.158]    [Pg.1449]   
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