Fracture thoughness

Bya] SEM, XRD, metallography Microhardness, plasticity and fracture thoughness of carbide coatings... 

J. Jancar, A.T. DiBenedetto, A. Dianselmo. Effect of adhesion on the fracture thoughness of calcium carbonate-filled polypropylene. Polym. Eng. Set., 33,559-563,1993. 

Deposits which are forming are frequentiy characterized by venting streams of hot (300°C) mineralized fluid known as smokers. These result in the local formation of metalliferous mud, rock chimneys, or mounds rich in sulfides. In the upper fractured zone or deep in the rock mass beneath the vents, vein or massive sulfide deposits may be formed by the ckculating fluids and preserved as the cmstal plates move across the oceans. These off-axis deposits are potentially the most significant resources of hydrothermal deposits, even though none has yet been located. 

If we then introduce a flaw into the system, by poking a pin into the inflated balloon, the balloon will explode, and all this energy will be released. The membrane fails by fast fracture, even though well below its yield strength. But if we introduce a flaw of the same dimensions into a system with less energy in it, as when we poke our pin into a partially inflated balloon, the flaw is stable and fast fracture does not occur. Finally, if we blow up the punctured balloon progressively, we eventually reach a pressure at which it suddenly bursts. In other words, we have arrived at a critical balloon pressure at which our pin-sized flaw is just unstable, and fast fracture just occurs. Why is this ... 

There are less exotic ways of increasing the strength of cement and concrete. One is to impregnate it with a polymer, which fills the pores and increases the fracture toughness a little. Another is by fibre reinforcement (Chapter 25). Steel-reinforced concrete is a sort of fibre-reinforced composite the reinforcement carries tensile loads and, if prestressed, keeps the concrete in compression. Cement can be reinforced with fine steel wire, or with glass fibres. But these refinements, though simple, greatly increase the cost and mean that they are only viable in special applications. Plain Portland cement is probably the world s cheapest and most successful material. 

Many fibrous composites are made of strong, brittle fibres in a more ductile polymeric matrix. Then the stress-strain curve looks like the heavy line in Fig. 25.2. The figure largely explains itself. The stress-strain curve is linear, with slope E (eqn. 25.1) until the matrix yields. From there on, most of the extra load is carried by the fibres which continue to stretch elastically until they fracture. When they do, the stress drops to the yield strength of the matrix (though not as sharply as the figure shows because the fibres do not all break at once). When the matrix fractures, the composite fails completely. 

After World War 11, dislocations had been taken up by some adventurous metallurgists, who held them responsible, in a purely handwaving (qualitative) manner and even though there was as yet no evidence for their very existence, for a variety of phenomena such as brittle fracture. They were claimed by some to explain everything imaginable, and therefore respectable scientists reckoned that they explained nothing. 

For cross-ply laminates, a knee in the load-deformation cun/e occurs after the mechanical and thermal interactions between layers uncouple because of failure (which might be only degradation, not necessarily fracture) of a lamina. The mechanical interactions are caused by Poisson effects and/or shear-extension coupling. The thermal interactions are caused by different coefficients of thermal expansion in different layers because of different angular orientations of the layers (even though the orthotropic materials in each lamina are the same). The interactions are disrupted if the layers in a laminate separate. 

The strength and extensibility of a noncrystallizable elastomer depend on its viscoelastic properties (28,29), even when the stress remains in equilibrium with the strain until macroscopic fracture occurs. In theory, such elastomers have a time- or rate-independent strength and ultimate elongation, but such threshold quantities apparently have not been measured, though rough estimates have been made (28,30). 

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