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Fractal and negative rate orders

I just mentioned that the order of a reaction can be any real number, even a negative one, but what does this actually mean  [Pg.139]

In the previous example we determined the rate order to be m = 1.5. How can we interpret this result Let s assume, we have the following reaction  [Pg.139]

We set the rate constant to 38 (for simplicity sake we do not worry about the units in this example, but you should work out the units of k for each rate order) and get the following data  [Pg.139]

This graph shows that the rate for the reaction with m=1.5 is between the two other rates. There is nothing special about this particular rate order - it just says that at concentrations of A 1 unit (here mM) the rate for m= 1.5 is faster than the rate for m=l. 0 and slower than the rate for m=2.0. [Pg.140]

Negative rate orders indicate inhibition of a reaction [Pg.140]


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