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Formation of the peroxy polymer radical

Macro-radicals formed during the initiation reaction react with oxygen molecules to produce peroxy polymer radicals (POO ) according to [Pg.431]

Polymer peroxy radicals have been detected by ESR [145, 146]. Typical spectra of polypropylene peroxy radicals are shown in Figs. 2a [Pg.431]


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Peroxy polymers

Peroxy radical formation

Peroxy radicals

Polymer radicals

Radical formation

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