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Formation of Single Bonds between Heavier Group 14 and 16 Elements

2 Formation of Single Bonds between Heavier Group 14 and 16 Elements [Pg.196]

1 Reaction of Group 14 Metal Halides with Chalcogenolate [Pg.196]

The most common method for the formation of M-E (M = Si, Ge, Sn E = S, Se, Te) bonds is the reaction of group 14 metal halides with chalcogenolate salts or chalcogenols/bases. Some recent examples are as follows. [Pg.196]

Compound M-E/A 8 slppm 8 Mlppm IJme Hz 8 dppm 8 Hlppm [Pg.196]

Compound M-EjA Elppm MlPpm JmeIHz clppm HlPpm [Pg.196]




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Bonding elements

Bonding single bonds

Elemental Bonds

Elemental formation

Elements bonds)

Elements formation and

Elements, formation

Formation of 1,2 and 2,3 bonds

Formation of bonds

Single bond formation

Single bonds

Single element

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