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Formation of Acyclic Fragments by Homodiene Prototropic shift

10 Formation of Acyclic Fragments by Homodiene Prototropic Shift [Pg.54]

The vinylcyclopropenes that bear an alkyl group cis to the double bond relieve the strain of the three membered via prototropic shift. Because of the geometric constraints, olefin geometry is controlled (Eq. 99). Olefination of the bifunctional [Pg.54]

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Fragment Formation

Prototropic

Prototropic shift

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