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Following chemical reactions. The EC mechanism

4 FOLLOWING CHEMICAL REACTIONS. THE EC MECHANISM The EC mechanism is of the type Electrode A3 n e At [Pg.418]

Qualitatively, we see that when K is small, the following homogeneous [Pg.418]

by combination with eqn. (186c) and the Nernst equation, we [Pg.419]

Fortunately for kx 1, eqns. (187) and (190) give the same result. Thus we can write the following diagnostic for an EC reaction at an RDE. [Pg.420]

For Nernstian behaviour at the DME, the equation for the half-wave potential is [Pg.420]

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