Fluoroxy compounds synthesis

Application of Fluoroxy Compounds to Organic Synthesis Electrophilic PHiiorination of Unsamrated Molecules Hesse, R. H Isr. J Chem 17, 60-70 43... 

John specialized in fluorine, boron, sulfur, phosphorus, and metal carbonyl chemistry. With M. Frederick Hawthorne, he discovered a series of amine complexes of aluminum trihydride and showed that some of them give aluminum metal when heated this process later became useful for the formation of aluminum thin films by chemical vapor deposition. One of his notable achievements was the discovery that the PPN cation, bisftriphenylphosphoranyhdene) ammonium, forms air-stable salts with many air-sensitive anions such as [Co(CO)4] . He also discovered that cesium fluoride can serve as a catalyst for the synthesis of organic fluoroxy compounds (RpOF) by the fluorination of acyl halides. 

An improved method of synthesis of fluoroxypentafluoroselenium SeFs-OF has been developed, viz. direct fluorination of the solid (KSeOFj ) formed by the addition of potassium fluoride to seleninyl fluoride. Treatment of the fluoroxy-compound with perfluorocyclopentene, carbon monoxide, and sulphur tetrafluoride has yielded the new compounds cyclo-CsF -O-SeF, SeFs O COF, and SeFs-O SFj, respectively. 

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