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Fluoroolefins phosphines

Coupling reactions and related fluoroalkylations with polytTuoioalkyl halides are induced by vanous reagents, among them metals such as copper and zinc, or by an electrochemical cell. More recently, examples of carbon-carbon bond forma tion by coupling of unsaturated fluorides have been reported Both acyclic and cyclic fluoroolefins of the type (Rp)2C=CFRp undergo reducUve dimerization on treatment with phosphines [42] (equation 33) The reaction shown in equation 33 IS also accompbshed electrocheimcally but less cleanly [43]... [Pg.304]

The addition of phosphines to fluoroolefins is of free radical nature [6, 7, 5]... [Pg.753]

Chloro- (69, 70) and fluoroolefins (69, 250, 511) also have been observed to form stable complexes upon reaction with tetrakis(triphenyl-phosphine)platinum(O). These show no C=C stretching band in the... [Pg.326]

See other pages where Fluoroolefins phosphines is mentioned: [Pg.119]    [Pg.183]   
See also in sourсe #XX -- [ Pg.753 , Pg.754 ]

See also in sourсe #XX -- [ Pg.753 , Pg.754 ]

See also in sourсe #XX -- [ Pg.753 , Pg.754 ]



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Fluoroolefins

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