Fluoronitro compounds oxidation

Nitrated fluoro compounds are synthesized by electrophilic (NOz+), radical (NO2 ), or nucleophilic (NO2-) methods Indirect nitration routes can suppress the side reactions associated with severe reaction conditions and some nitration reagents Novel fluoronitro compounds, unobtainable by direct nitration, can also be pre pared For example, the nitration of (2-fluoro-2,2-dinitroethoxy)acetaldoxime followed by oxidation of the nitroso intermediate with hydrogen peroxide yields 2-fluoro-2,2-dinitioethyl 2,2-dinitroethyl ether [f] (equation 1)... 

Nitro compounds are oxidized at carbon bonded to nitro group 2-Fluoronitro compounds and stlyl mtronates are converted to 2-fluorocarbonyl compounds by ceric ammonium salt [7/] (equation 73)... 

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