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Fluoroalkyl sulfides anodic substitutions

By the way, trifluoroacetaldehyde is a versatile fluoro building block. However the chemical or electrochemical oxidative transformation of trifluoro-ethanol to trifluoroacetaldehyde has been unsuccessful. Trifluoroacetaldehyde is therefore generally produced by the reduction of trifluoroacetic acid ester or acid chloride using an excess of LAH. The anodic substitution at fluoroalkyl phenyl sulfides is a useful alternative because it realizes the transformation of economical trifluoroethanol to highly valuable trifluoroacetaldehyde equivalents as shown in Scheme 6.5. [Pg.21]

See other pages where Fluoroalkyl sulfides anodic substitutions is mentioned: [Pg.26]    [Pg.28]    [Pg.28]    [Pg.35]    [Pg.66]    [Pg.75]    [Pg.17]    [Pg.19]    [Pg.19]    [Pg.26]    [Pg.1039]    [Pg.70]    [Pg.101]   
See also in sourсe #XX -- [ Pg.66 , Pg.67 , Pg.68 , Pg.69 , Pg.70 , Pg.71 , Pg.72 , Pg.73 , Pg.74 ]



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Anodic substitution

Fluoroalkylation

Fluoroalkyls

Substituted sulfides

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