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Fluoroalkyl amines, anodic

The reaction proceeds via electrogenerated cationic intermediates as is seen in the anodic oxidation of nonfluorinated amines, carbamates, and amides (Scheme 19). However, the regiochemistry in these processes is not governed by the stability of the cationic intermediates 1 and r because the main products are formed via the less stable intermediates I. Indeed, the promotion effect and unique re-gioselectivity observed in reactions of the fluoroalkyl amines can be explained mainly in terms of the a-CH kinetic acidities of the cation... [Pg.78]

Regioselective anodic methoxylation of more complicated N-(tetrafluoropropyl)amines 23 is also successful as shown in Eq. 60. Methoxylation takes place at the fluoroalkyl group preferentially. ... [Pg.79]

See other pages where Fluoroalkyl amines, anodic is mentioned: [Pg.37]    [Pg.407]    [Pg.77]    [Pg.5070]    [Pg.28]    [Pg.26]    [Pg.83]    [Pg.17]   


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