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2-fluoro-l-iodododecane

A mixture of potassium hydrogen fluoride, 1 M hydrofluoric acid and (V-iodosuccinimide in the presence of tetrabutylammonium fluoride (TBAF) as a phase-transfer catalyst has been shown to effect iodofluorination of alkenes in good yield.163 Dodec-l-ene (6) has been transformed to 2-fluoro-l-iodododecane (7) in 82% yield. TBAF is essential for the reaction to proceed quickly and to improve the yield. The percentage of the side product 1-iodododecan-2-ol is kept to a minimum (0.2%). Many alkenes have been transformed to the corresponding fluoroiodo derivatives by this method.163... [Pg.581]

See other pages where 2-fluoro-l-iodododecane is mentioned: [Pg.125]    [Pg.125]    [Pg.582]    [Pg.342]    [Pg.342]    [Pg.342]    [Pg.125]    [Pg.125]    [Pg.582]    [Pg.342]    [Pg.342]    [Pg.342]    [Pg.125]   
See also in sourсe #XX -- [ Pg.48 ]

See also in sourсe #XX -- [ Pg.72 ]



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