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Fluoro carbon complexes stability

Our group has devoted two articles for the study of systems where the chiral subunits are bonded to a boron or to a metallic atom (Scheme 3.28). In both cases, the weakness of the bonds formed can be easily broken. In the first case, a series of bisdiphenylborates and the effect of the fluoro substitution on the relative stability of the homo vs. heterochiral complexes have been studied by means of DFT calculations (B3LYP/6-31G ) [29]. In addition, the corresponding isoelectronic structures, in which the boron has been substituted by a carbon or a positively charged nitrogen, have been considered. In all the cases, the homo and heterochiral complexes present D2 and S4 symmetries, respectively. [Pg.74]


See other pages where Fluoro carbon complexes stability is mentioned: [Pg.250]    [Pg.389]    [Pg.376]    [Pg.146]    [Pg.146]    [Pg.260]    [Pg.440]    [Pg.546]    [Pg.233]    [Pg.146]    [Pg.260]    [Pg.7]    [Pg.20]    [Pg.5]   
See also in sourсe #XX -- [ Pg.267 ]




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Carbon complex

Carbon stability

Carbon stabilization

Carbonate complexation

Carbonate) complexes

Carbonates, stability

Complex Stabilization

Complexation stabilization

Fluoro carbon complexes

Fluoro complexes

Stability complexes

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