Fluonnation with perchloryl

The fluonnation of both mono and dinitro enolates proceeds well with perchloryl fluoride. The mononitro fluorinated intermediates have been used to develop fluorinated materials of general synthetic utility [III, 113] (equation 63)... 

Perchloryl fluoride, well known for its ability to fluonnate organic substrates, has become a reagent with limited appeal. Its loss of popularity stems from difficult... 

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