Fluid regular solution theory

This equation shows that the excess Gibbs free energy computed from a cubic EOS of the van der Waals type and the one-fluid mixing rules contains three contributions. The first, which is the Flory free-volume term, comes from the hard core repulsion terms and is completely entropic in nature. The second term is very similar to the excess free-energy term in the regular solution theory, and the third term is similar to a term that appears in augmented regular solution theory. Consequently, one is led... 

Hydrogen [54] and helium [55] atoms are known to exhibit regular/chaotic dynamics in the presence of external field of different colors and intensities. Chaotic ionization from the Rydberg states of the atoms [54,55] has been very intriguing for the experimentalists. Both QFD [56,57] and quantum theory of motion (QTM) [58,59] have been able to explain the quantum domain behavior of the classically chaotic systems [60], In QFD, the quantum dynamics is mapped onto that of a probability fluid of density and current density p(r, t) and j(r, t) respectively obtainable as solutions to the QFD equations. The fluid moves under the influence of the classical Coulomb potential augmented by a quantum potential defined as... 

Hildebrand and Rotariu [14] have considered differences in heat content, entro])v and activity and classified solutions as ideal, regular, athermal, associated and solvated. Despite much fundamental work the theory of binary liquid mixtures is still e.ssentiaUy unsatisfactory as can be seen from the. systematic treatment of binar> mi.Ktures by Mauser-Kortiim [15]. The thermodynamics of mixtures is presented most instructively in the books of Mannchen [16] and Schuberth [17]. Bittrich et al. [17a] give an account of model calculations concerning thermophysical properties of juire and mixed fluids. 

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