Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Flavonols cobalt catalysts

Copper complexes were used as efficient catalysts for selective autoxidations of flavonols (HFLA) to the corresponding o-benzoyl salicylic acid (o-BSH) and CO in non-aqueous solvents and at elevated temperatures (124-128). The oxidative cleavage of the pyrazone ring is also catalyzed by some cobalt complexes (129-131). [Pg.442]

Cobaltn-Schiff base complexes, e.g. Co(salen),567 Co(acacen)568 and cobalt(II) porphyrins,569 e.g. Co(TPP), are effective catalysts for the selective oxygenation of 3-substituted indoles to keto amides (equation 249), a reaction which can be considered as a model for the heme-containing enzyme tryptophan-2,3-dioxygenase (equation 21).66 This reaction has been shown to proceed via a ternary complex, Co-02-indole, with probable structure (175), which is converted into indolenyl hydroperoxide (176). Decomposition of (176) to the keto amide (174) readily occurs in the presence of Co(TPP), presumably via formation of a dioxetane intermediate (177).569,56 Catalytic oxygenolysis of flavonols readily occurs in the presence of Co(salen) and involves a loss of one mole of CO (equation 251).570... [Pg.388]


See other pages where Flavonols cobalt catalysts is mentioned: [Pg.7193]   
See also in sourсe #XX -- [ Pg.388 ]

See also in sourсe #XX -- [ Pg.388 ]

See also in sourсe #XX -- [ Pg.6 , Pg.388 ]




SEARCH



Cobalt catalyst

Cobalt catalysts catalyst

Flavonol

Flavonoles

© 2024 chempedia.info